Category X Axis - This is a line along which labels for the chart's categories are arranged. Categories are individual measurements intervals or groupings for the original data. In column charts, the category axis is the horizontal line along the bottom.
Value Y Axis - This is vertical for column charts.

microsoft excel docs

The X axis or category axis is always the horizontal axis along the bottom of your chart

microsoft excel docs

The Y axis or value axis is always the vertical axis which is usually on the left of your chart.

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